Deuteronomy 5:27 records the people asking Moses to mediate, which is exactly why Moses stood between them as stated in v.5.

In Deuteronomy 5:24, the people acknowledge seeing God's glory yet surviving – confirming the fear that made Moses stand between them.

Deuteronomy 18:15 promises a prophet like Moses – connecting his mediatory role in Deut 5:5 to a future greater mediator.

Deuteronomy 18:18 expands the prophecy of a prophet like Moses who will speak God's words – typologically fulfilled in Christ, echoing Moses' role in Deut 5:5.

Deuteronomy 34:10 declares no prophet arose like Moses, whom God knew face to face – underscoring the unique mediatory position described in Deut 5:5.

Exodus 19:16 describes the terrifying theophany that caused the people's fear, explaining why Moses stood as mediator in v.5.

Exodus 20:18-21 gives the full account of the people's fear and request for Moses as mediator, directly paralleling the role in v.5.

Exodus 24:2 shows the same event: only Moses could approach God while people stayed back, confirming his unique mediator role.

Exodus 24:3 depicts Moses declaring God's words to the people, exactly the mediating action described here.

Psalm 106:23 recalls Moses standing in the breach to turn away God's wrath — another example of his mediatorial intercession.

Galatians 3:19 directly references the law being given through an intermediary, explaining the role Moses played.

Hebrews 12:18-24 contrasts the fearful Sinai event mediated by Moses with the joyful Mount Zion mediated by Christ.

Exodus 18:19 has Jethro telling Moses to represent the people before God, reinforcing his role as mediator.

In Exodus 19:3, Moses first goes up the mountain to receive God's word – the event recalled in Deut 5:5 where he stood as mediator.

Exodus 19:17 shows Moses bringing the people to the mountain – the context for his mediating role in Deut 5:5.

Exodus 20:21 depicts Moses drawing near to God while people stay far off – directly matching Deut 5:5's description.