Deuteronomy 21:9
So shalt thou put away the guilt of innocent blood from among you, when thou shalt do that which is right in the sight of the Lord.
Cross-reference
Deuteronomy 19:13 uses the exact phrase 'purge the guilt of innocent blood from Israel', directly paralleling the command here.
Deuteronomy 19:12 shows the concrete action of handing over a murderer to the avenger, implementing the purge of innocent blood.
Deuteronomy 13:18 repeats the condition 'doing what is right in the sight of the Lord', the same standard for purging bloodguilt.
In 1 Kings 2:31, David orders Joab's execution to remove bloodguilt from his house — a direct application of the legal principle in Deuteronomy.
In 2 Kings 21:16, Manasseh fills Jerusalem with innocent blood, the opposite of purging it — showing failure to obey the law.
In Psalm 106:38, innocent blood pollutes the land — the same problem Deuteronomy 21:9's ritual aimed to cleanse.